No.107
Acetoxylation of Vinyl Bromide
| A1540 | Copper(I) Acetate (1) |
5g |
Generally, the synthesis of vinyl acetates is difficult when vinyl halides are used as starting materials. However, the use of 1 allows the reaction to produce vinyl acetate relatively easily.1) For example, heating an acetonitrile solution of 1-bromocyclohexene with excess of 1 provides a mild and simple means for convertion into 1-acetoxycyclohexene.1a)
References
1) Vinyl acetates from vinyl bromides
a) G. W. Klumpp, H. Bos, M. Schakel, R. F. Schmitz, J. J. Vrielink, Tetrahedron Lett., 1975, 3429.
b) A. Commercon, J. Normant, J. Villieras, J. Organomet. Chem., 93, 415 (1975).
a) G. W. Klumpp, H. Bos, M. Schakel, R. F. Schmitz, J. J. Vrielink, Tetrahedron Lett., 1975, 3429.
b) A. Commercon, J. Normant, J. Villieras, J. Organomet. Chem., 93, 415 (1975).
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