| TCI产品编码 : | I0079 | ||||||||||||||
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| 库存情况 : |
2012年02月09号上午06点的情况 *2012年4月前，中国库存将暂时显示上海仓库和天津仓库的库存总和。 |
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| 纯度 / 分析方法 : | >98.0%(T) | ||||||||||||||
| 保存温度 : | |||||||||||||||
| 分子式 / 分子量 : | C15H21FeO6=353.17 | ||||||||||||||
| CAS编码 : | 14024-18-1 | ||||||||||||||
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| MDL编码 : | MFCD00000020 | ||||||||||||||
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| 国内危险化学品编码 : | |||||||||||||||
| mp : | 185 °C |
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Efficient Fe/Cu Co-Catalyzed C-N Cross-Coupling Reaction Typical procedure (Entry 1): A Schlenk tube is charged with p-anisidine (92.4 mg), K2CO3 (138 mg), Fe(acac)3 (34.4 mg), and Cu(OAc)2• H2O (20 mg). Under a nitrogen atmosphere, 4-bromotoluene (85.5 mg) is added followed by dry DMF (0.8 mL). The reaction mixture is then heated to 135 ºC, and stirred for 20 h. The mixture is cooled to room temperature and diluted with diethyl ether. The resulting suspension is filtered through a celite pad and the filtrate is concentrated. The residue is purified by column chromatography on silica gel (eluent: petroleum ether/ethyl acetate) to give 4-methoxy-N-p-tolylaniline (98.1 mg, 92 %). |
| F & F : | 6, 304 |
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| RTECS# : | NO8960000 |
| TCI产品学术记录 : |
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| 相关分类 : |
Structure of Chemicals
Classes of Metal Compounds
Transition Metal Compounds
Fe (Iron) Compounds
Synthetic Organic Chemistry Catalysts for Organic Synthesis Homogeneous Catalysts Metal Complexes Synthetic Organic Chemistry Catalysts for Organic Synthesis Homogeneous Catalysts Iron Synthetic Organic Chemistry Ion-Catalyzed Oraganic Synthesis Iron catalysts Functional Materials Oxidation Environmentally-friendly Oxidation Transition Metal Complexes (Environmentally-friendly Oxidation) |