| TCI产品编码 : | C1383 | ||||||||||||||
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| 库存情况 : |
2012年02月04号上午06点的情况 *2012年4月前，中国库存将暂时显示上海仓库和天津仓库的库存总和。 |
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| 纯度 / 分析方法 : | |||||||||||||||
| 保存温度 : | |||||||||||||||
| 分子式 / 分子量 : | C55H46OP3Rh=918.80 | ||||||||||||||
| CAS编码 : | 17185-29-4 | ||||||||||||||
| 相关CAS编码 : | |||||||||||||||
| MDL编码 : | MFCD00151644 | ||||||||||||||
| 监管条件代码 : | |||||||||||||||
| 国内危险化学品编码 : | |||||||||||||||
Rh(I)-catalyzed synthesis of indoles through the amino-Claisen rearrangement of N-propargylanilines Typical procedure: Under an argon atmosphere, to a solution of carbonyltris(triphenylphosphine)rhodium(I) hydride (16 micro-mol) in 1,1,1,3,3,3-hexafluoro-2-propanol (1 mL) is added N-2-butynyl-N-benzyl-4-methoxyaniline (0.4 mmol) in 1,1,1,3,3,3-hexafluoro-2-propanol (1.5 mL) at an ambient temperature, and the mixture is refluxed until the consumption of the substrate by TLC analysis. The mixture is diluted with ether and filtered through a Celite pad. After concentration of the filtrate to dryness, purification by silica gel chromatography (hexane/AcOEt = 25:1) gives the corresponding indole in 99% yield. |
| Merck Index(14) : | 9758 |
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| F & F : | 7, 53 |
| UN编号 : | 2811 |
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| Class : | 6.1 |
| PG : | III |
| 相关分类 : |
Structure of Chemicals
Classes of Metal Compounds
Transition Metal Compounds
Rh (Rhodium) Compounds
Synthetic Organic Chemistry Catalysts for Organic Synthesis Homogeneous Catalysts Metal Complexes Synthetic Organic Chemistry Catalysts for Organic Synthesis Homogeneous Catalysts Rhodium |
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