结构式
| TCI产品编码 : | C1383 | ||||||||||||||
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| 库存情况 : |
2010年09月03号上午06点的情况 *日本库存的产品大约在两周到货。 |
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| 分子式 / 分子量 : | C55H46OP3Rh=918.78 | ||||||||||||||
| CAS编码 : | 17185-29-4 | ||||||||||||||
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| MDL编码 : | MFCD00151644 | ||||||||||||||
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| 国内危险化学品编码 : | |||||||||||||||
Rh(I)-catalyzed synthesis of indoles through the amino-Claisen rearrangement of N-propargylanilines Typical procedure: Under an argon atmosphere, to a solution of carbonyltris(triphenylphosphine)rhodium(I) hydride (16 micro-mol) in 1,1,1,3,3,3-hexafluoro-2-propanol (1 mL) is added N-2-butynyl-N-benzyl-4-methoxyaniline (0.4 mmol) in 1,1,1,3,3,3-hexafluoro-2-propanol (1.5 mL) at an ambient temperature, and the mixture is refluxed until the consumption of the substrate by TLC analysis. The mixture is diluted with ether and filtered through a Celite pad. After concentration of the filtrate to dryness, purification by silica gel chromatography (hexane/AcOEt = 25:1) gives the corresponding indole in 99% yield. |
| Merck Index(14) : | 9758 |
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| F & F : | 7, 53 |
| UN编号 : | 2811 |
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| Class : | 6.1 |
| PG : | III |
| 相关分类 : |
Structure of Chemicals
Classes of Metal Compounds
Transition Metal Compounds
Rh (Rhodium) Compounds
Synthetic Organic Chemistry Catalysts for Organic Synthesis Homogeneous Catalysts Metal Complexes Synthetic Organic Chemistry Catalysts for Organic Synthesis Homogeneous Catalysts Rhodium |
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