| TCI产品编码 : | B3161 | ||||||||||||||
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| 库存情况 : |
2012年02月09号上午06点的情况 *2012年4月前，中国库存将暂时显示上海仓库和天津仓库的库存总和。 |
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| 纯度 / 分析方法 : | >98.0%(T) | ||||||||||||||
| 保存温度 : | Freezer | ||||||||||||||
| 分子式 / 分子量 : | C24H54P2Pd=511.06 | ||||||||||||||
| CAS编码 : | 53199-31-8 | ||||||||||||||
| 相关CAS编码 : | |||||||||||||||
| MDL编码 : | MFCD03094580 | ||||||||||||||
| 监管条件代码 : | |||||||||||||||
| 国内危险化学品编码 : | |||||||||||||||
Newman-Kwart Rearrangement of Thiocarbamates Typical Procedure: An ampoule is charged with the thiocarbamate (0.442 mmol) and anhydrous degassed toluene (4 mL) is added via gastight syringe under nitrogen with stirring. A J. Youngs valve is fitted and the ampoule is placed into an oil bath pre-equilibrated at 100℃. After ca. 5 minutes the valve is removed and Pd(t-Bu3P)2 (2 mol%, 0.00884 mmol) is added as a solid, the valve is then replaced and the reaction mixture heated for 2.5 hours. A sample of the reaction mixture is removed via gastight syringe and found to contain the desired product (＞99%). |
| TCI MAIL : | |
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| TCI产品学术记录 : | |
| 相关分类 : |
Structure of Chemicals
Classes of Metal Compounds
Transition Metal Compounds
Pd (Palladium) Compounds
Synthetic Organic Chemistry Catalysts for Organic Synthesis Homogeneous Catalysts Metal Complexes Synthetic Organic Chemistry Catalysts for Organic Synthesis Homogeneous Catalysts Palladium Synthetic Organic Chemistry Suzuki-Miyaura Cross-coupling Palladium Catalyst (for Suzuki-Miyaura Cross-coupling) |