| TCI产品编码 : | B2027 | ||||||||||||||||||
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| 库存情况 : |
2012年02月09号上午06点的情况 *2012年4月前，中国库存将暂时显示上海仓库和天津仓库的库存总和。 |
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| 纯度 / 分析方法 : | >96.0%(T) | ||||||||||||||||||
| 保存温度 : | |||||||||||||||||||
| 分子式 / 分子量 : | C34H28FeP2=554.39 | ||||||||||||||||||
| CAS编码 : | 12150-46-8 | ||||||||||||||||||
| 相关CAS编码 : | |||||||||||||||||||
| MDL编码 : | MFCD00001422 | ||||||||||||||||||
| 监管条件代码 : | |||||||||||||||||||
| 国内危险化学品编码 : | |||||||||||||||||||
Synthesis of Carbinols Typical procedure: Under an air atmosphere, a Schlenk tube is charged with Cu(OAc)2•H2O (4.0 mg, 0.02 mmol), dppf (16.6 mg, 0.03 mmol), arylboronic acid (0.4 mmol), aldehyde (0.2 mmol), NaOAc (49.2 mg, 0.6 mmol), and toluene (3 mL) under ice-salt (-20 ºC). The mixture is stirred for 0.5 h at room temperature, refluxed for 24 h, and then cooled in a Schlenk tube to room temperature. The mixture is extracted with ethyl acetate (4×5 mL), and the organic layers are washed with water. The organic layers are dried over MgSO4, concentrated, and purified by flash column chromatography on silica gel to give the desired product. |
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| TCI产品学术记录 : | |
| 相关分类 : |
Structure of Chemicals
Classes of Metal Compounds
Transition Metal Compounds
Fe (Iron) Compounds
Synthetic Organic Chemistry Suzuki-Miyaura Cross-coupling Phosphine Ligands (for Suzuki-Miyaura Cross-coupling) Structure of Chemicals Metallocenes Ferrocenes Synthetic Organic Chemistry Phosphines Synthetic Organic Chemistry Ligands Phosphine Ligands |