| TCI产品编码 : | B1138 | ||||||||||||||
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| 库存情况 : |
2012年02月09号上午06点的情况 *2012年4月前，中国库存将暂时显示上海仓库和天津仓库的库存总和。 |
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| 纯度 / 分析方法 : | >98.0%(GC) | ||||||||||||||
| 保存温度 : | |||||||||||||||
| 分子式 / 分子量 : | C27H26P2=412.45 | ||||||||||||||
| CAS编码 : | 6737-42-4 | ||||||||||||||
| 相关CAS编码 : | |||||||||||||||
| MDL编码 : | MFCD00003050 | ||||||||||||||
| 监管条件代码 : | |||||||||||||||
| 国内危险化学品编码 : | |||||||||||||||
| mp : | 63 °C |
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Synthesis of aromatic esters via Pd-catalyzed decarboxylative coupling with bidentate phosphine ligands Typical procedure: A 10 mL oven-dried Schlenk tube is charged with Pd(OAc)2 (0.005 mmol), 1,3-bis(diphenylphosphino)propane (0.0075 mmol), and potassium ethyl oxalate (0.75 mmol). The tube is evacuated and backfilled with argon. Bromobenzene (0.5 mmol) and 1-methyl-2-pyrrolidone (1.0 mL), are added by syringe at room temperature. The tube is then sealed and the mixture is allowed to stir under 1 atm of argon at 150ºC for 24 h (the tube is connected to the Schlenk line which is filled with argon so that CO2 can be released to air). |
| TCI产品学术记录 : | |
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| 相关分类 : |
Synthetic Organic Chemistry
Suzuki-Miyaura Cross-coupling
Phosphine Ligands (for Suzuki-Miyaura Cross-coupling)
Synthetic Organic Chemistry Phosphines Synthetic Organic Chemistry Ligands Phosphine Ligands |